The assignee for this patent, patent number 8784769, is
Reporters obtained the following quote from the background information supplied by the inventors: "Currently, 95% or more of the total supply of hydrogen peroxide is produced by an anthraquinone process. However, this anthraquinone process requires a procedure for regenerating an anthraquinone solution and a procedure for separating hydrogen peroxide from an anthraquinone solution and refining the separated hydrogen peroxide because many reaction steps are required to produce hydrogen peroxide and side products are formed in side reactions of the reaction steps [
"In order to solve the problems of an anthraquinone process, research into reactions for directly producing hydrogen peroxide from oxygen and hydrogen that do not produce side products other than water has been being made for a long period of time, but this research is not commercially available yet due to technical difficulties. This research is problematic as follows.
"First, there is a problem with mixing oxygen and hydrogen. That is, a mixture of oxygen and hydrogen can very easily explode because it has a large explosive range depending on the mixing ratio of oxygen and hydrogen. When the concentration of hydrogen in air at a pressure of 1 atm is 4.about.75 mol %, the mixture can be exploded by an ignition source. Here, when oxygen is used instead of air, the explodable concentration of hydrogen is enlarged to 4.about.94 mol %. This explodable concentration of hydrogen is enlarged depending on the increase of pressure, thus increasing the explodability of the mixture [
"In addition to the above safety problem, there is another problem, which is that hydrogen peroxide, although produced, easily decomposes into water and oxygen because it is a very unstable compound, and it is not easy to acquire high hydrogen peroxide selectivity because a catalyst used to produce hydrogen peroxide is used to synthesize water. Therefore, in conducting research into reactions for directly producing hydrogen peroxide from oxygen and hydrogen, strong acids and halide additives together with high-activity catalysts have been researched in order to solve the above problems.
"Reactions for directly producing hydrogen peroxide have been conducted using precious metal catalysts, such as gold, platinum, palladium and the like [
"Further, in order to improve the selectivity of hydrogen peroxide, acid is added to a solvent to prevent hydrogen peroxide from decomposing into water and oxygen, and halogen ions are added to a solvent or a catalyst to prevent oxygen and hydrogen from forming water [Y.-F. Han,
"Recently, various methods using nanotechnologies have been attempted in order to develop a high-activity catalyst which can be efficiently used to directly produce hydrogen peroxide from oxygen and hydrogen. For example, Q. Liu et al. developed a catalyst in which palladium nanoparticles are supported on active carbon (Q. Liu,
"As described above, the method of directly producing hydrogen peroxide from oxygen and hydrogen has been researched for a long period of time due to its technical importance, but is still being researched academically and is limited to research into small-scale catalyst production and catalytic reaction. Therefore, in order to commercialize this method, it is keenly required to develop a catalyst which can be easily produced and which can exhibit remarkably excellent performance even under the reaction condition that additives, such as acids, halogen ions and the like, are used at a minimum."
In addition to obtaining background information on this patent, NewsRx editors also obtained the inventors' summary information for this patent: "Hereupon, the present inventors have made efforts to develop a catalyst which can be produced and which can exhibit high activity in the production of hydrogen peroxide. As a result, they found that a catalyst in which a polymer electrolyte multilayer film containing metal particles is formed on a carrier can be used to obtain a high yield of hydrogen peroxide compared to conventional catalysts and that this catalyst exhibits high activity even under the condition that only a very small amount of halogen ions is added without the addition of acids. Based on the findings, the present disclosure was completed.
"Accordingly, the present disclosure provides a catalyst which can exhibit high activity in various reactions.
"Further, the present disclosure provides a method of forming a polymer electrolyte multilayer film containing metal particles on a carrier.
"Furthermore, the present disclosure provides a method of directly producing hydrogen peroxide from oxygen and hydrogen using the catalyst.
"An aspect of the present disclosure provides a catalyst, including: a carrier; a polymer electrolyte multilayer film formed on the carrier; and metal particles dispersed in the polymer electrolyte multilayer film.
"Another aspect of the present disclosure provides a method of preparing a catalyst, including: forming a polymer electrolyte multilayer film on a carrier; dispersing metal precursors in the polymer electrolyte multilayer film; and reducing the metal precursors to metals using a reducing agent.
"Still another aspect of the present disclosure provides a method of preparing a catalyst, including: forming a polymer electrolyte multilayer film complexed with metal precursors on a carrier; and reducing the metal precursors to metal particles using a reducing agent.
"Still another aspect of the present disclosure provides a method of producing hydrogen peroxide from hydrogen and oxygen using the catalyst.
"As described above, the catalyst according to the present disclosure discloses that metal particles are strongly bonded between the layers of a polymer electrolyte multilayer film, so that the elution of metal does not occur during a reaction, with the result that the activity of the catalyst does not deteriorate. Further, the catalyst according to the present disclosure discloses that the kind and pH of polymer electrolytes and the layer number of the polymer electrolyte multilayer film are adjusted, thus adjusting the concentration and particle size of the metal dispersed in the polymer electrolyte multilayer film. Furthermore, the catalyst according to the present disclosure discloses that it can be easily prepared, and in that it can be used to increase activity in various reactions using metal particles as a catalyst as well as to produce hydrogen peroxide."
For more information, see this patent: Chung, Young Min; Kwon,
Keywords for this news article include: Gases, Anions, Chemistry, Palladium, Chalcogens, Anthracenes, Electrolytes, Heavy Metals, Hydrocarbons, Nanoparticle, Anthraquinones, Nanotechnology, Hydrogen Peroxide, Inorganic Chemicals, Transition Elements, Emerging Technologies,
Our reports deliver fact-based news of research and discoveries from around the world. Copyright 2014, NewsRx LLC
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