VACNFs, which hold promise for genedelivery tools, sensors, batteries and other technologies, are typically manufactured by placing a substrate coated with nickel nanoparticles in a vacuum chamber heated to 700°C (1292°F). The chamber is filled with ammonia gas and either acetylene or acetone gas, which contain carbon, and a voltage is applied to the substrate and an anode in the chamber to ionize the gas, creating plasma that directs the nanofiber growth.
"This discovery makes VACNF manufacture safer and cheaper, because you don't need to account for the risks and costs associated with ammonia gas," said Anatoli Melechko, an adjunct associate professor of materials science and engineering at
Ammonia has been used in the process to keep carbon from forming a crust on the nanoparticles, which would prevent the formation of VACNF. "We didn't think we could grow VACNFs without ammonia or a hydrogen gas," Melechko said. The team tried the conventional vacuum technique, using acetone gas. When they replaced the ammonia gas with ambient air, it worked. The size, shape and alignment of the nanofibers also were consistent with the fibers produced using conventional techniques.
"We did this using the vacuum technique without ammonia," Melechko said. "But it creates the theoretical possibility of growing VACNF without a vacuum chamber. If that can be done, you would be able to create VACNF on a much larger scale." Melechko also credited the role of two high school students involved in the work, A. Kodumagulla and V.
The paper, "Aerosynthesis: Growth of Vertically-aligned Carbon Nanofibres with Air DC Plasma," is published online in the journal Nanomaterials and Nanotechnology. Co-authors include former NC State doctoral student
For more information, see www.ncsu.edu. ME
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