News Column

Researchers Submit Patent Application, "Filtering Medium for Fluid Purification", for Approval

February 25, 2014

By a News Reporter-Staff News Editor at Life Science Weekly -- From Washington, D.C., NewsRx journalists report that a patent application by the inventors Gore, Avinash (Johnstown, PA); Hu, Bo (Greensburg, PA); Luk, Sydney (Cherry Hill, NJ), filed on February 7, 2012, was made available online on February 13, 2014 (see also HOGANAS AB (Publ)).

The patent's assignee is HOGANAS AB (Publ).

News editors obtained the following quote from the background information supplied by the inventors: "Toxic inorganic/organic substances in various water sources have to be reduced below regulated levels before the water goes into drinking water systems or is released into recipients.

"Nitrate (NO.sub.3.sup.-) is a common inorganic contaminant found in groundwater in the areas where agriculture activities occur heavily. Nitrates usually come from fertilizers, used in farming and gardening in order to provide the plants and shrubs with nutrients.

"Other contaminants which may be generated from such activities are phosphates (PO.sub.4.sup.3-) and traces of pesticides such as atrazine. Accumulation of fertilizers is a problem as they can go through the soil and contaminate ground water systems. Both shallow water wells and deep water wells can be affected.

"Toxic metals such as arsenic (As), chromium (Cr), whereof its oxidation state +6 (Cr.sup.VI) is regarded as most harmful, lead (Pb), mercury (Hg), cadmium (Cd), selenium (Se), etc, other substances as chlorinated hydrocarbons and other organic substances, sometimes measured as Total Organic Carbon (TOC) are generated either from natural origins or from industrial or farming activities.

"Other types of contaminants that may be present in the water are microorganisms, such as bacteria.

"A conventional method for killing bacteria is the use of the chlorination process where chlorine containing chemical substances is added to the water for disinfection. Chlorine is a highly efficient disinfectant, however one of the drawbacks with this process is the remaining chlorine compounds in the water, such as CIO.sup.- ions which can cause health problems.

"In order to reach acceptable levels of contaminants in drinking water, several processes are currently used.

"Reverse osmosis is based on the process of osmosis. This involves the selective movement of water from one side of a membrane to the other. This technique is also very energy consuming.

"The ion exchange process percolates water through bead-like spherical resin materials (ion-exchange resins). Ions in the water are exchanged for other ions fixed to the beads. Microorganisms can attach to the resins, providing a culture medium for rapid bacterial growth and subsequent pyrogen generation. This technique has a low initial capital investment but a high long-term operational cost.

"One of the above techniques is usually applied to target one, or in some cases two contaminants present in the water. This means that several techniques often need to be applied following each other, in a chain process. In order to increase the efficiency, reducing costs, it would be desirable to purify the water from several contaminants in one single step. However, today there are few products available in the market capable of effectively purifying water from multiple contaminants simultaneously.

"US patent publication no. 2007/0241063A1 describes a process for treating water contaminated with a volatile organic compound with iron powder granules containing iron, carbon and oxygen.

"U.S. Pat. No. 5,534,154 describes a procedure for treating contaminated water by passing the water containing contaminant in solution through a permeable body of treatment material comprising particles of an adsorptive material physically mixed with particles of metal. The iron metal particles mentioned in the patent are iron fillings generally in solid granular form. The procedure requires a negative Eh voltage which in turn demands oxygen exclusion.

"U.S. Pat. No. 6,827,757 describes a magnetite-iron based composite with very small average particle size of 0.05-10 .mu.m.

"EP 1273371A2 describes an iron powder adapted to remediate selected media by dehalogenating halogenated hydrocarbons in the media comprising iron powder particles and inorganic compounds. Said inorganic compounds should have a very low electric resistivity, and are preferably selected from the group consisting of Ca, Ti, V and Cr. Said inorganic compounds should be present on at least a portion of the surface of each particle.

"WO 2008/129551 discloses a liquid filter medium comprising carbonaceous material, a water-insoluble metal oxide or hydroxide, and at least one of chitosan and an ion exchanger.

"U.S. Pat. No. 4,642,192 discloses a method of reducing the concentration of inorganic chlorine by passing water through a bed of metal particles, brass. This method shows insignificant effect on reduction of nitrate.

"U.S. Pat. No. 6,303,039 discloses a formulation comprising at least two biocide metals and at least one chelating agent, wherein said formulation dissolves over a period of months or longer.

"WO 03/076341 describes a system for control of bacterial growth in water comprising antimicrobial treatment media within a containment vessel, the treatment media including one or more of transition metals and transition metal oxides.

"U.S. Pat. No. 6,261,986 provides a method for producing a pollutant adsorption and degradation article and the article itself. At least one adsorbent is mixed with at least one pollutant transforming agent to form a mixture. This mixture is compacted to form a porous highly permeable article. Zeolites or surface modified zeolites, SMZ, are proposed as adsorbent and iron powder or iron in combination with other metals such as silver are proposed as pollutant transforming agent. Reduction of chromate and perchloroethylene in water was using the article was demonstrated.

"U.S. Pat. No. 6,942,807 provides a water filter device and method which removes heavy metals and organic compounds from raw water. The device comprises at least one iron filter connected in series to a sand filter.

"In US 2006/0021946 the use of volcanic rock or recycled minerals from anthropogenic brick to remove toxic metals from contaminated aqueous solutions is disclosed. The volcanic rock or recycled minerals from anthropogenic brick may be combined with zero valent iron, oxidized iron derivates and activated carbon.

"The published patent application US 2009/0218266 discloses an ion delivery system, IDS, that comprises a source of metal ions with biocidal properties and a matrix that immobilizes the source of ions and provides a sustained release of ions at biocidal concentrations. Such source may be metal salts, metal particles or particulate metallic alloy. Silver combined with various metals are disclosed. The particle size of the metals or alloys being from 5 to 2 000 nm, preferably under 1 000 nm and most preferably between 100-300 nm.

"US 2010/0176044 provides a carbonaceous filtering media for treating drinking water. In some embodiments the filtering media contains silver as an antimicrobial component.

"The published application WO2010/019934 provides a process for removing virus from drinking water comprising filtering drinking water through a layer of coarse sand and contacting the drinking water with a composite iron matrix. The composite iron matrix comprises components containing iron, manganese, cerium, carbon phosphorous, sulfur, aluminum silicon, chromium, copper and zinc."

As a supplement to the background information on this patent application, NewsRx correspondents also obtained the inventors' summary information for this patent application: "It is previously known that silver containing powder can kill bacteria when the content of silver is greater than certain percentage but have very little effect on the reduction of nitrate. It is also previously known that iron containing powders can only reduce insignificant amounts of nitrate.

"The inventors of the present invention have now surprisingly found that using a combination of silver and iron in powder form, a significant synergetic and/or catalyst effect can be obtained which is shown in a surprisingly enhanced capability of killing bacteria and reducing nitrate and chlorine. Thus such combination can reduce significant amounts of heavy metals, bacteria, chlorine and nitrate simultaneously. The synergetic effect can be achieved by optimizing the combination through choosing the type of iron powder and silver powder, determining the amount of silver, and the method of preparing the iron-based filtering medium containing silver.

"The filtering medium according to the present invention may also be used for reducing other contaminants such as nitrites, heavy metals, such as As, Cr, especially Cr having the most stable state at oxidation stage +6, Pb, Hg, toxic organic and inorganic compounds, other microorganisms or combinations thereof.

"The present invention relates to a filtering medium for reducing the content of contaminants in fluids, wherein said filtering medium comprises iron and silver in a form chosen from at least one of:--a mixture (A) comprising a major part of an atomized iron-based or iron powder and a minor part of a silver powder; --an iron-silver powder alloy (B); and --a silver containing iron-based porous and permeable composite (C); and wherein said contaminants are selected from the group consisting of chlorine containing compounds, nitrates, nitrites, heavy metals, toxic inorganic substances, toxic organic compounds, microorganisms and/or combinations thereof. The present invention also relates to a method for reducing the content of contaminants in fluids comprising the steps of:

"a) providing a filtering medium comprising iron and silver in a form chosen from at least one of: a mixture (A) containing a major part of an iron-based powder and a minor part of a silver powder, an iron-silver alloy (B), and a silver containing iron-based porous and permeable composite (C),

"b) bringing one or more contaminated fluid(s) in contact with the filtering medium to purify said one or more fluid(s),

"c) optionally removing the filtering medium from the purified one or more fluid(s).

"Further, the present invention relates to a method for the production of a filtering medium comprising iron and silver in a form chosen from at least one of: a mixture (A) containing a major part of an iron-based powder and a minor part of a silver powder, an iron-silver alloy (B), and a silver containing iron-based porous and permeable composite (C), wherein

"the mixture (A) is obtained by mixing atomized iron powder with at least essentially pure Ag powder particles;

"the iron-silver alloy (B) is obtained by thermal bonding and/or alloying iron-based powder particles with silver powder particles;

"the silver containing iron-based porous and permeable composite (C) is obtained by subjecting a mixture (A) containing a major part of an iron-based powder and a minor part of a silver powder or an iron-silver powder alloy (B), to one or more of the following steps: compaction, heat treatment and sizing.

"The present invention also relates to use of a filtering medium in a fluid, preferably a water containing fluid, more preferably ground water, river water, industrial waste water, civic waste water, medical waste water and/or surface water for reducing the content of contaminants selected from the group consisting chlorine containing compounds, nitrates, nitrites, heavy metals, toxic inorganic substances, toxic organic compounds, microorganisms and/or combinations thereof in the fluid.


"FIG. 1 shows a schematic drawing of a column test used for evaluating the performance of the filtering medium according to the invention.

"FIG. 2 illustrates example of pure silver powder with 100%

"FIG. 3 is a schematic illustration of thermal bonding and thermal alloying silver particles to the surface of iron particles."

For additional information on this patent application, see: Gore, Avinash; Hu, Bo; Luk, Sydney. Filtering Medium for Fluid Purification. Filed February 7, 2012 and posted February 13, 2014. Patent URL:

Keywords for this news article include: Anions, Nitrates, Treatment, Nitric Acid, HOGANAS AB (Publ), Organic Chemicals.

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Source: Life Science Weekly

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