ENP Newswire -
Release date- 30012014 - EPFL scientists have uncovered the mechanism by which novel, revolutionary solar cells based on lead iodide perovskite light-absorbing semiconductor transfer electrons along their surface.
The finding shows these devices constitute a new type of solar cells and open the way to the design of photovoltaic converters with improved efficiency.
Photovoltaic energy conversion offers one of the best means for the future of renewable energy in the world. The efficiency of solar cells depends heavily upon the light-absorbing materials they use. Photovoltaic systems based on lead halide perovskite are a new, revolutionary type of device with efficiencies currently exceeding 16 %. However, a detailed description of how these solar cells turn light into electrical current is still lacking. Publishing in Nature Photonics, scientists from EPFL have investigated how the generated electrical charge travels across the perovskite surface of solar cells built with various architectures.
Lead halide perovskites are materials that have recently attracted an immense interest, as solar cells based on these semiconductors demonstrate very high conversion efficiencies and an unsurpassed cell voltage of more than 1 Volt. However, it is not entirely clear how they work. A better understanding of their functioning mechanisms would help improve them in the future or even open up novel technologies with increased efficiency.
An EPFL group led by
The results showed two main dynamics. First, that charge separation, the flow of electrical charges after sunlight reaches the perovskite light-absorber, takes place through electron transfer at both junctions with titanium dioxide and the hole-transporting material on a time scale as short as 100 femtoseconds (10-13 s). Secondly, the researchers found that charge recombination was significantly slower for titanium oxide films rather than aluminum ones. Charge recombination is a detrimental process degrading the converted energy into heat and thus reducing the overall efficiency of the solar cell.
The authors state that lead halide perovskites constitute unique semiconductor materials in solar cells, allowing ultrafast transfer of electrons and positive charges at two junctions simultaneously and transporting both types of charge carriers quite efficiently. In addition, their findings show a clear advantage of the architecture based on titanium dioxide films and hole-transporting materials.
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